(OC-6-33)-(2,2′-Bipyridine-κ2N,N′)trimethyl(2-methylsulfanyl-2-thiazoline-κN)platinum(IV) tetrafluoridoborate
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چکیده
منابع مشابه
(OC-6-33)-(2,2′-Bipyridine-κ2 N,N′)trimethyl(2-methylsulfanyl-2-thiazoline-κN)platinum(IV) tetrafluoridoborate
The asymmetric unit of the title complex, [Pt(CH(3))(3)(C(10)H(8)N(2))(C(4)H(7)NS(2))]BF(4), contains two crystallographically independent mol-ecules. The Pt(IV) atom in each complex cation exhibits a distorted octa-hedral coordination geometry, built up by three methyl ligands in a facial binding fashion, a bipyridine ligand and a monodentately N-bound 2-methyl-sulfanyl-2-thia-zoline ligand (c...
متن کامل(OC-6-35)-(2,2′-Bipyridine-κ2 N,N′)dimethyl(3-sulfidopropionato-κ2 S,O)platinum(IV)
The title complex, [Pt(CH(3))(2)(SCH(2)CH(2)CO(2))(C(10)H(8)N(2))], is formed by the unusual oxidative addition of the disulfide, R(2)S(2) (R = CH(2)CH(2)CO(2)H), to (2,2'-bipyridine)-dimethyl-platin-um(II) with elimination of RSH. The product contains an unusual six-membered thiol-ate-carboxyl-ate chelate ring. This slightly distorted octa-hedral complex exhibits cis angles ranging from 77.55 ...
متن کاملrac-(OC-6-33)-bis[2-(N-Benzylmethyliminomethyl-κN)-1H-imidazol-1-ido-κN 1]bis(ethylamido)titanium(IV)
The title compound, [[Ti(C(2)H(10)N)(2)(C(11)H(10)N(3))(2)] or Ti(C(11)H(10)N(3))(2)(NEt(2))(2)], was prepared by direct reaction of 2-(N-phenyl-methyl-imino-meth-yl)-1H-imidazole and [Ti(NEt(2))(4)]. The Ti(IV) atom is in a pseudo-octa-hedral coordination environ-ment with the imidazolido-group N-atoms occupying apical positions and amido- and imino-N-atoms cis-located in the equatorial plane....
متن کامل(2,2′-Bipyridine)(2-formyl-6-methoxyphenolato)nickel(II) perchlorate
In the title compound, [Ni(C(8)H(7)O(3))(C(10)H(8)N(2))]ClO(4), the Ni(II) atom is in a slightly distorted square-planar coordination by two N atoms from the 2,2'-bipyridine (bipy) ligand and two O atoms from the deprotonated 2-formyl-6-methoxy-phenolate (mbd) ligand. The bipy ligand is nearly coplanar with the Ni(II) square plane, the Ni atom being only 0.042 (2) Å from the mean plane, whereas...
متن کاملPhenotype and differentiation patterns of the oval cell lines OC/CDE 6 and OC/CDE 22 derived from the livers of carcinogen-treated rats.
An electron microscopic, immunocytochemical, and enzyme cytochemical analysis of the previously established oval cell lines OC/CDE 6 and OC/CDE 22 was performed to characterize the phenotype and differentiation patterns of long-term cultures of oval cells. It was found that alpha-fetoprotein, albumin, and cytokeratin 19 are present in all cultured cells. This indicates that oval cells constitut...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810027546